Polyolefin Miscibility: Solid-State NMR Investigation of Phase Behavior in Saturated Hydrocarbon Blends
نویسندگان
چکیده
منابع مشابه
Miscibility of Polyolefin Blends
Phase separation in polymers is important for many technical applications but is difficult to predict theoretically. Recently, extensive experimental studies on the miscibility of polyolefins revealed that these systems display a wider variety of mixing behavior than their chemical similarity suggests. In order to predict phase diagrams of polyolefin blends from pure component properties, we ha...
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The large variation in miscibility of blends of polyolefins is related to the architecture of the chain molecules. In this paper we present first results of an approach in which small scale simulations of local interactions are combined with an analytical model for the thermodynamics, the Born-Green-Yvon lattice model, to predict phase diagrams of polyolefin blends from the pure component prope...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2003
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma0301449